At All Around Compounding Co., Ltd. (All Around Polymer Co., Ltd.), we specialize in high-quality engineering plastics, including customized nylon composites. PA6 (Nylon 6) and PA66 (Nylon 66) are two of the most widely used polyamides in various applications. Understanding the differences between PA6 and PA66, including their material properties, density, and melting points, is crucial for engineers and manufacturers to make informed decisions.
This comprehensive guide provides a detailed comparison of PA6 and PA66, focusing on their key characteristics, advantages, and typical applications in industries like automotive, electronics, and sports equipment. With our extensive industry experience, we offer essential insights to help you choose between PA6 for its flexibility and PA66 for its high-stress applications.

PA6 and PA66 Material Properties: Key Differences and Applications in Engineering Plastics
PA6 (Nylon 6) and PA66 (Nylon 66) are both high-performance nylons known for their mechanical strength, thermal resistance, and versatility. However, their structural and material differences make each suitable for specific applications:
PA6 (Nylon 6):
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Easier to process due to its lower melting point.
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Offers better impact resistance and greater flexibility.
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More cost-effective, making it suitable for general applications.
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Tends to absorb more moisture, which may affect dimensional stability.
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Has lower tensile strength compared to PA66.
PA66 (Nylon 66):
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Known for superior tensile strength and rigidity.
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Better suited for high-temperature and high-stress applications.
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Offers enhanced dimensional stability due to lower water absorption.
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Requires higher processing temperatures and is generally more expensive.
Key Differences Between PA6 and PA66
Here's a detailed comparison chart to help you choose between PA6 and PA66 based on key properties and applications:
Properties |
PA6 |
PA66 |
Molecular Structure | Single repeating unit | Two repeating units |
Density (g/cm³) | 1.13 | 1.14 |
Melting Point (°C) | 220 | 260 |
Water Absorption | Higher | Lower |
Crystallinity | Lower | Higher |
Tensile Strength (MPa) | Lower | Higher |
Impact Resistance (kJ/m²) | Higher | Lower |
Thermal Stability (°C) | Continuous use up to 180°C | Continuous use up to 200°C |
Processing Temperature (°C) | 230 - 250 | 270 - 290 |
Molding Temperature (°C) | 80 - 100 | 90 - 120 |
Molding Shrinkage (%) | 0.6 | 0.8 |
Heat Deflection Temperature (°C) | 170 | 250 |
Applications | Automotive parts, Office furniture, Bicycles | High-stress automotive parts, Electrical components, Sports equipments |
PA6 and PA66 Compounds: Enhancing Properties with Composites
The choice between Nylon 6 (PA6) and Nylon 66 (PA66) primarily depends on the specific requirements of your project. Both materials offer valuable performance characteristics, and the decision should be based on application needs such as strength, rigidity, and heat resistance, referencing the comparison chart above.
Nylon 6 (PA6)
Nylon 6 is known for its high ductility, ease of processing, and cost-effectiveness, making it ideal for general applications such as flexible automotive parts, office furniture, and bicycle components.
Nylon 66 (PA66)
Nylon 66 offers superior strength, rigidity, and heat resistance, making it suitable for high-stress automotive parts, electrical components, and high-performance sports equipment.
PA6 and PA66 Compounds: Enhancing Properties with Composites
For more demanding requirements, PA6 and PA66 can be modified or reinforced with various fillers to enhance their original properties and expand their range of applications. These modified or reinforced nylons are referred to as nylon compounds. Reinforcing PA6 and PA66 with fillers like glass fiber, carbon fiber, or impact modifiers can improve their properties:
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Increased Strength and Stiffness: Reinforcing PA6 and PA66 with glass or carbon fibers results in composites that can handle higher loads and stress without deforming. (Read more: Top Plastics for Metal Replacement in Manufacturing : Benefits, Choices, and Analysis)
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Enhanced Thermal Properties: By adding specific fillers, the heat resistance of these nylons can be improved, allowing them to maintain performance at elevated temperatures. (Read more: How to Select Car Headlight Housing Materials)
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Improved Dimensional Stability: Reduced water absorption and enhanced rigidity help maintain the shape and size of components, even in variable environmental conditions.
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Improved Toughness: Impact modifiers can significantly improve the toughness of nylon composites, making them ideal for applications where durability and resistance to sudden forces are critical. These modifiers help absorb and dissipate energy, reducing the risk of material failure under impact. (Read more: Enhance Nylon Durability and Flexibility with the Right Impact Modifier)
Composite Type | Enhancements |
Glass Fiber Reinforced | Enhances strength, stiffness, and dimensional stability. Used in automotive components, power tools, and sports equipment. |
Mineral-Filled | Improves rigidity and thermal stability. Commonly used in electrical housings and structural parts. |
Flame-Retardant | Provides safety in electrical and electronic applications, used in connectors and switches. |
Carbon Fiber Reinforced | Offers excellent strength-to-weight ratio and electrical conductivity. Used in aerospace, automotive, and high-performance sports equipment. |
Impact Modified | Increases toughness and resistance to impact forces, reducing fracture risks. Suitable for applications requiring enhanced durability and shock absorption. |


Applications of PA6 and PA66
PA6 and PA66 are widely used in various industries due to their unique properties. Here's a look at some common applications:
PA6 Applications
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Automotive Industry: PA6 is used in the production of flexible parts such as steering column, seat belt buckle, and side mirror assembly due to its good impact resistance and moderate tensile strength.
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Office Furniture: PA6 is utilized in manufacturing various office furniture components, offering good flexibility and durability.
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Bicycles: PA6 is employed in the production of bicycle parts, providing necessary flexibility and impact resistance for different components.
PA66 Applications
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High-Stress Automotive Parts: PA66 is preferred for high-stress parts such as engine components, manifold, fuel rail and water tank cover owing to its superior tensile strength and higher thermal stability.
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Electrical Components: PA66 is used in connectors, switches, and other high-performance electrical components where rigidity and dimensional stability are crucial.
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Sports Equipment: PA66 is ideal for applications requiring high mechanical strength and rigidity. It is commonly used in the production of ski bindings, helmets, and protective gear, providing durability and safety in demanding sports environments.
FAQ: Frequently Asked Questions About PA6 and PA66
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Which nylon type is better for high-temperature environments? PA66, due to its higher melting point and thermal stability.
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What are the cost considerations between PA6 and PA66? PA6 is generally more cost-effective, while PA66 offers superior strength and rigidity at a higher cost.
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Can PA6 and PA66 be recycled? Yes, both are recyclable, making them environmentally friendly options.
Case Study: Tailored Solutions for Our Clients
At All Around Compounding Co., Ltd. (All Around Polymer Co., Ltd.), we pride ourselves on our customer-centric approach and our ability to provide the best material solutions for our clients' needs. Here's a case study highlighting how we helped a client choose the optimal material for their application:
Client Background:
A leading automotive parts manufacturer approached us with a challenge. They were developing a new line of engine components and were uncertain whether to use PA6 or PA66 for their project. They needed a material that could withstand high temperatures and stress while maintaining dimensional stability.
Our Approach:
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Initial Consultation: We started with a detailed consultation to understand their specific needs, performance requirements, and the operational environment of the components.
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Material Analysis: Based on their requirements, we conducted a thorough analysis comparing the properties of PA6 and PA66.
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Recommendation: Given the high-stress and high-temperature conditions, we recommended PA66 due to its superior tensile strength, thermal stability, and lower water absorption.
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Prototype Development: We assisted in developing prototypes using our high-quality PA66 composites, ensuring they met all performance criteria.
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Testing and Feedback: The prototypes were rigorously tested under real-world conditions. The client provided feedback, and we made minor adjustments to optimize performance.
Outcome:
The client successfully launched their new line of engine components, which performed exceptionally well under high-stress conditions. Our PA66 composites provided the necessary strength and stability, contributing to the product's overall success. The client praised our attentive service, expertise, and the high quality of our materials.
Conclusion
Whether you choose PA6 for its flexibility and impact resistance or PA66 for strength and heat resistance, both materials offer distinct advantages that can be further enhanced with composite technology.
Moreover, reinforcing PA6 and PA66 with materials like glass fiber, impact modifiers or carbon fibers can significantly enhance their mechanical properties, allowing them to achieve better performance in demanding applications. This reinforcement enables these nylons to handle greater stress and environmental challenges, making them more versatile and reliable for various industrial uses.
Need help choosing the right nylon for your project?
Ready to choose the right material for your application? Contact us at info@aaccl.com for expert advice and high-quality nylon composite solutions tailored to your needs.